N-Chlorination of secondary amides. I. Kinetics of N-chlorination of N-methyl acetamide
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چکیده
منابع مشابه
N-Methyl-N-(2-methylphenyl)acetamide
In the title compound, C(10)H(13)NO, the N atom and the methyl group are almost coplanar with the benzene ring to which they are bonded [deviations of 0.131 (1) and 0.038 (1) Å, respectively, from the ring plane]. In the crystal structure, inter-molecular C-H⋯O hydrogen bonds form a three-dimensional network. Mol-ecules are stacked parallel to the b-axis direction.
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In the title compound, C(18)H(16)N(2)O(2)·H(2)O, the dihedral angle between the quinoline ring system and the benzene ring is 87.19 (8)°. In the crystal, water mol-ecules are linked to acetamide mol-ecules via inter-molecular O-H⋯N and O-H⋯O hydrogen bonds.
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The title compound, C(10)H(13)ClN(2)O, was obtained as a by-product in the reaction of 2-chloro-methyl-1H-benzimidazole, dimethyl sulfate and toluene to synthesise 2-chloro-methyl-1-methyl-benzimidazole. The dihedral angle between the benzene ring and the acetamide group is 89.72 (6)° while that between the aromatic ring and the chloracetyl group is 84.40 (4)°. In the crystal, adjacent mol-ecu...
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In this study, the densities, excess molar volumes and partial molar volumes of four binary systems containing N,N-dimethyl acetamide (DMAc) with 1-alkanols (1-butanol up to 1-heptanol) are measured at 298.15 K. The results showed both constructive and expansive excess volumetric behavior for studying binary mixtures. Deviation values of heavy alcohol have more positive and less negative excess...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1969
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v69-423